Citric acid has three pKa’s:
pKa1 = 3.13
pKa2 = 4.72
pKa3 = 6.40
The desired buffer pH (100 mM sodium citrate buffer) is 6.0 which is close to pKa3 = 6.40, According to my understanding Pka3 exists between sodium citrate dibasic and tr
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