Time-resolved and temperature-dependent photoluminescence were recorded using an electrically gated intensified charge-coupled device (ICCD) camera (Andor iStar DH740 CCI-010) connected to a calibrated grating spectrometer (Andor SR303i). Pulsed 500 nm photoexcitation was provided at a repetition rate of 1 kHz from a home-built non-collinear optical parametric amplifier (NOPA) powered by a Ti:sapphire amplifier (Spectra Physics Solstice Ace) that generated 100 fs duration pulses centred at 800 nm. A 550 nm long-pass filter (Thorlabs) was used to prevent scattered laser signal from entering the camera. Temporal evolution of the PL emission was obtained by stepping the ICCD gate delay with respect to the excitation pulse. The minimum gate width of the ICCD was 3 ns. For temperature-dependent measurements, the sample was mounted in a helium cryostat and kept under high vacuum (10−5 mbar).
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