3.2.4. Calculation of Theoretical Tg with the Gordon–Taylor Equation

RD Rong Di
JL Jingwen Liu
HG Holger Grohganz
TR Thomas Rades
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Theoretical Tg was calculated with the Gordon–Taylor equation:

where Tg12 and Tg1 are the Tg of the co-amorphous samples and the components and ωi is the mass fraction of the component i. K is a constant and can be calculated by the equation:

where ρ1 and ρ2 are the densities of the two components (ρamorphous−CAR = 1.24 g/cm3) [22]. No information for the amorphous TRP was available in the literature, so it was calculated by the following equation:

where ρcrystalline−CAR = 1.26 g/cm3, ρcrystalline−TRP = 1.30 g/cm3 [22,23].

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