Differential electrochemical mass spectrometry (DEMS)

YW Yuesheng Wang
ZF Zimin Feng
PC Peixin Cui
WZ Wen Zhu
YG Yue Gong
MG Marc-André Girard
GL Gilles Lajoie
JT Julie Trottier
QZ Qinghua Zhang
LG Lin Gu
YW Yan Wang
WZ Wenhua Zuo
YY Yong Yang
JG John B. Goodenough
KZ Karim Zaghib
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The DEMS experiments were performed with a commercial quadrupole mass spectrometer (Hiden Analytical) and a house-made Swagelok-type cell with K0.4Ni0.2Mn0.8O2 as cathode, sodium as anode and 1 M NaPF6 in ethylene carbonate (EC)/diethyl carbonate (DEC) (4:6 in volume) as electrolyte. The electrochemical test for DEMS is performed on a LAND battery testing system at room temperature. The carrier gas is high purity Ar-gas with a flow rate of 0.5 mL min−1.

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