Phenylboronic (0.15 mmol), aryl halide (0.1 mmol), base (0.2 mmol), and catalyst (5 mg) were stirred vigorously in deionized water (2 mL) at 90 °C for 5 h under mild stirring. The yields of reaction products were analyzed by GC (Agilent 7890A). All the productions were separated and the spectra of 1HNMR were provided in supporting information.
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