4′-p-tolyl-2,2′:6,2″-terpyridine (ttpy), 4′-p-methyltolyl-2,2′:6,2″-terpyridine (mettpy), 4′-p-fluorotolyl-2,2′:6,2″-terpyridine (fttpy) were prepared as described by Wang and Hanan13 Ir(ttpy)Cl3, Ir(mettpy)Cl3 and Ir(fttpy)Cl3 were prepared based on the procedure reported by Chirdon et al.13.
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