3.3. Absorption and Emission Spectra, Photoluminescence Quantum Yield

PG Pavel S. Gribanov
DL Dmitry A. Loginov
DL Dmitry A. Lypenko
AD Artem V. Dmitriev
SP Sergey I. Pozin
AA Alexey E. Aleksandrov
AT Alexey R. Tameev
IM Igor L. Martynov
AC Andrey Yu. Chernyadyev
SO Sergey N. Osipov
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UV–VIS spectra were measured using an AvaSpec-2048 spectrophotometer (Avantes, The Netherlands). The photoluminescence spectra were recorded at 77 K and 298 K, on the Fluorolog-3 spectrofluorometer system (HORIBA Jobin Yvon S.A.S., France). The excitation source was a 450 W Xenon lamp with Czerny-Turner double monochromators, the registration channel was a R928 photomultiplier with Czerny-Turner double monochromators). Pulsed xenon lamp (150 W) was used for phosphorescence spectra and phosphorescence decay curve measurements. The phosphorescence decay curves were analyzed using the FluoroEssenceTM software for calculation of the phosphorescence lifetime values. Quantum yields of solid films photoluminescence and solution photoluminescence were measured by the absolute method. Light of photoluminescence was collected by Quanta-φ F-3029-sphere linked with Fluorolog 3 by Fiber-Optics adaptor FL-3000 produced by Horiba Jobin Yvon S.A.S. (France) Photoluminescence quantum yields were calculated by FluoroEssenceTM software.

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