Synthesis of heteroleptic bis(dipyrrinato)zinc(II) coordination copolymers, Co-1-k

A methanol solution (5 ml) of zinc(II) acetate (5 μmol) was added to a dichloromethane solution (10 ml) of H2L1 and H2L3 (the amounts of the ligands are listed in Fig. 1C). After several days, powdery solid was formed in the reaction mixture, which was collected by filtration, washed with methanol and dichloromethane, and then dried to obtain Co-1-k.

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